Angelina Jolie & Brad Pitt – Still Finalizing

When it comes to newsworthy couples, Brad Pitt and Angelina Jolie are top of the list. They met on set while working on Mr & Mrs. Smith while Pitt was still married to Jennifer Aniston. But they grew close on set, and after Pitt and Aniston’s split was finalized, that they announced their relationship.

They had three children, adopted three more, and eventually married in a chateau in France in 2014. But the marriage lasted just two years, and they announced their separation. They still haven’t resolved their divorce; with ownership of the chateau they got married in remaining a particularly hot topic. They’ve both been declared single, though.